| 세션명 | Virtual Lightning Session |
|---|---|
| 발표장 | Online (10/20~10/22) |
| 논문코드 | VPS-41 |
| 발표일 | --2020 |
| 발표시간 | |
| 논문제목 | n-Doping of Single-walled Carbon Nanotubes Using Pyridine-boryl Radicals |
| 발표자 | Naoki Tanaka |
| 발표자 소속 | Kyushu University |
| 저자 | Naoki Tanaka, Aoi Hamasuna, Tsuyohiko Fujigaya† |
| 소속 | Kyushu University |
| 논문초록 | The chemical doping of single-walled carbon nanotubes (SWCNTs) using electron donor and acceptor molecules is a crucial step for controlling the frontier orbital energy gap of SWCNTs. This means that SWCNTs are a promising material for electronics applications such as thermoelectric conversion and thin-film transistors, due to their flexibility, stability and light weight. Among all chemical dopants, 2 organic dopants containing hetero atoms are important materials as they permit fine controllability of the doping level; they also provide stability due to the flexibility of their structural design. In this study, we found that pyridine-boryl (py-boryl) radicals serve as efficient electron-doping reagents for SWCNTs, in which the doping mechanism comprises electron transfer from the py-boryl radical to the SWCNT. The formation of a stable py-boryl cation is essential for efficient doping; the captodative effect of the py-boryl cation is important to this process. |
THE POLYMER SOCIETY OF KOREA